Anthracite

Anthracite coal
Black coal, hard coal, stone coal, blind coal, Kilkenny coal, crow coal, craw coal, black diamond
Metamorphic rock

Anthracite coal

Anthracite coal
Composition
Carbon, 92.1‒98%

Anthracite is a hard, compact variety of coal that has a submetallic luster. It has the highest carbon content, the fewest impurities, and the highest calorific content of all types of coal except for graphite.

Anthracite is the most metamorphosed type of coal (but still represents low-grade metamorphism), in which the carbon content is between 92.1% and 98%.[1][2] The term is applied to those varieties of coal which do not give off tarry or other hydrocarbon vapours when heated below their point of ignition. Anthracite ignites with difficulty and burns with a short, blue, and smokeless flame.

Anthracite is categorized into standard grade, which is used mainly in power generation, and high grade (HG) and ultra high grade (UHG), the principal uses of which are in the metallurgy sector. Anthracite accounts for about 1% of global coal reserves,[3] and is mined in only a few countries around the world. China accounts for the majority of global production; other producers are Russia, Ukraine, North Korea, South Africa, Vietnam, the UK, Australia and the US. Total production in 2010 was 670 million tons.[4]

Names

An American culm pile.

Anthracite derives from the Greek anthrakítēs (ἀνθρακίτης), literally "coal-like".[5] Other terms which refer to anthracite are black coal, hard coal, stone coal,[6][7] dark coal, coffee coal, blind coal (in Scotland),[8] Kilkenny coal (in Ireland),[6] crow coal or craw coal, and black diamond. "Blue Coal" is the term for a once-popular and trademarked brand of anthracite, mined by the Glen Alden Coal Company in Pennsylvania, and sprayed with a blue dye at the mine before shipping to its northeastern U.S. markets to distinguish it from its competitors.

Culm has different meanings in British and American English.

Properties

Anthracite (Ibbenbüren, Germany)
Anthracite (near Bay City, Michigan)

Anthracite is similar in appearance to the mineraloid jet and is sometimes used as a jet imitation.

Anthracite differs from ordinary bituminous coal by its greater hardness (2.75–3 on the Mohs scale[9]), its higher relative density of 1.3–1.4, and luster, which is often semi-metallic with a mildly brown reflection. It contains a high percentage of fixed carbon and a low percentage of volatile matter. It is also free from included soft or fibrous notches and does not soil the fingers when rubbed. Anthracitization is the transformation of bituminous coal into anthracite.

The moisture content of fresh-mined anthracite generally is less than 15 percent. The heat content of anthracite ranges from 22 to 28 million Btu per short ton (26 to 33 MJ/kg) on a moist, mineral-matter-free basis. The heat content of anthracite coal consumed in the United States averages 25 million Btu/ton (29 MJ/kg), on the as-received basis (i.e., containing both inherent moisture and mineral matter). Since the 1980s, anthracite refuse or mine waste has been used for coal power generation in a form of recycling. The practice known as reclamation is being applied to culm piles antedating laws requiring mine owners to restore lands to their approximate original condition.

Chemically, anthracite may be considered as a transition stage between ordinary bituminous coal and graphite, produced by the more or less complete elimination of the volatile constituents of the former, and it is found most abundantly in areas that have been subjected to considerable earth-movement metamorphic stresses and pressures, such as the flanks of great mountain ranges. Anthracite is associated with strongly deformed sedimentary rocks that were subjected to higher pressures and temperatures (but short of metamorphic conditions) just as bituminous coal is generally associated with less deformed or flat-lying sedimentary rocks. For example, the compressed layers of anthracite that are deep mined in the folded Ridge and Valley Province of the Appalachian Mountains of the Coal Region of East-central Pennsylvania are extensions of the same layers of bituminous coal that are mined on the generally flat lying and undeformed sedimentary rocks further west on the Allegheny Plateau of Kentucky and West Virginia, Eastern Ohio, and Western Pennsylvania. In the same way the anthracite region of South Wales is confined to the contorted portion west of Swansea and Llanelli, the central and eastern portions producing steam coal, coking coal and domestic house coals.

Structurally, anthracite shows some alteration by the development of secondary divisional planes and fissures so that the original stratification lines are not always easily seen. The thermal conductivity is also higher; a lump of anthracite feels perceptibly colder when held in the warm hand than a similar lump of bituminous coal at the same temperature. The chemical composition of some typical anthracites is given in the article coal.

Anthracite has a history of use in blast furnaces for iron smelting; however, it lacked the pore space of metallurgical coke, which eventually replaced anthracite.[10]

History of mining and use

Anthracite coal breaker and power house buildings, New Mexico, circa 1935

In southwest Wales, anthracite has been burned as a domestic fuel since at least medieval times,[11] when it was mined near Saundersfoot. More recently, large scale mining of anthracite took place right across the western part of the South Wales Coalfield until the late 20th century. Mining continues but now on a smaller scale.

In the United States, anthracite coal history began in 1790 in Pottsville, Pennsylvania, with the discovery of coal made by the hunter Necho Allen in what is now known as the Coal Region. Legend has it that Allen fell asleep at the base of Broad Mountain and woke to the sight of a large fire because his campfire had ignited an outcropping of anthracite coal. By 1795, an anthracite-fired iron furnace had been built on the Schuylkill River.

Anthracite was first experimentally burned as a residential heating fuel in the US on 11 February 1808, by Judge Jesse Fell in Wilkes-Barre, Pennsylvania, on an open grate in a fireplace. Anthracite differs from wood in that it needs a draft from the bottom, and Judge Fell proved with his grate design that it was a viable heating fuel.

In spring 1808, John and Abijah Smith shipped the first commercially mined load of anthracite down the Susquehanna River from Plymouth, Pennsylvania, marking the birth of commercial anthracite mining in the United States. From that first mine, production rose to an all-time high of over 100 million tons in 1917.

Anthracite usage was inhibited by the difficulty of igniting it. This was a particular concern in smelting iron using a blast furnace. With the invention of hot blast in 1828, which used waste heat to preheat combustion air, anthracite became a preferred fuel, accounting for 45% of US pig iron production within 15 years.[12] Anthracite for iron smelting was later displaced by coke.

From the late 19th century until the 1950s, anthracite was the most popular fuel for heating homes and other buildings in the northern US, until it was supplanted by oil burning systems and more recently natural gas systems. Many large public buildings, such as schools, were heated with anthracite-burning furnaces through the 1980s.

Anthracite is a "fighting fuel", World War II poster

During the American Civil War, Confederate blockade runners used anthracite as a smokeless fuel for their boilers to avoid giving away their position to the blockaders.[13]

The invention of the Wootten firebox enabled locomotives to directly burn anthracite efficiently, particularly waste culm. In the early 20th century US, the Delaware, Lackawanna & Western Railroad started using only the more expensive anthracite coal in its passenger locomotives, dubbed themselves "The Road of Anthracite," and advertised widely that travelers on their line could make railway journeys without getting their clothing stained with soot. The advertisements featured a white-clad woman named Phoebe Snow and poems containing lines like "My gown stays white / From morn till night / Upon the road of Anthracite". Similarly, the Great Western Railway in the UK was able to use its access to anthracite (it dominated the anthracite region) to earn a reputation for efficiency and cleanliness unmatched by other UK companies.

Internal combustion motors driven by the so-called "mixed", "poor", "semi-water" or "Dowson gas" produced by the gasification of anthracite with air (and a small proportion of steam) were at one time the most economical method of obtaining power - consuming 1 pound of fuel per horsepower-hour, or less. Large quantities of anthracite for power purposes were formerly exported from South Wales to France, Switzerland and parts of Germany. Widespread commercial anthracite mining in Wales has now ceased although a few large open cast sites remain, along with some relatively small drift mining operations.

Anthracite today

American football trophy custom-made from anthracite

Anthracite generally costs two to three times as much as regular coal. In June 2008, the wholesale cost of anthracite was US$150/short ton.[14]

The principal use of anthracite today is for a domestic fuel in either hand-fired stoves or automatic stoker furnaces. It delivers high energy per its weight and burns cleanly with little soot, making it ideal for this purpose. Its high value makes it prohibitively expensive for power plant use. Other uses include the fine particles used as filter media, and as an ingredient in charcoal briquettes. Anthracite is an authorised fuel[15] in terms of the United Kingdom's Clean Air Act 1993, meaning that it can be used within a designated Smoke Control Area such as the central London boroughs.

Mining

China today mines by far the largest share of global anthracite production, accounting for more than three-quarters of global output.[4] Most Chinese production is of standard-grade anthracite, which is used in power generation. Increased demand in China has made that country into a net importer of the fuel, mostly from Vietnam, another major producer of anthracite for power generation, although increasing domestic consumption in Vietnam means that exports may be scaled back.[16]

Current U.S. anthracite production averages around 5 million tons per year. Of that, about 1.8 million tons were mined in the state of Pennsylvania.[17] Mining of anthracite coal continues to this day in eastern Pennsylvania, and contributes up to 1% to the gross state product. More than 2,000 people were employed in the mining of anthracite coal in 1995. Most of the mining as of that date involved reclaiming coal from slag heaps (waste piles from past coal mining) at nearby closed mines. Some underground anthracite coal is also being mined. As petroleum and natural gas have become more expensive, anthracite coal may grow in its importance as an energy source.[18]

Countries producing HG and UHG anthracite include Russia and South Africa. HG and UHG anthracite are used as a coke or coal substitute in various metallurgical applications (sintering, PCI, direct BF charge, pelletizing). It plays an important role in cost reduction in the steel making process and is also used in production of ferro-alloys, silicon-manganese, calcium-carbide and silicon-carbide. South Africa exports lower-quality, higher-ash anthracite to Brazil to be used in steel-making.

Sizing and grading

Anthracite is processed into different sizes by what is commonly referred to as a breaker (see coal). The large coal is raised from the mine and passed through breakers with toothed rolls to reduce the lumps to smaller pieces. The smaller pieces are separated into different sizes by a system of graduated sieves, placed in descending order. Sizing is necessary for different types of stoves and furnaces.

Anthracite is classified into three grades, depending on its carbon content. Standard grade is used as a domestic fuel and in industrial power-generation. The rarer higher grades of anthracite are purer – i.e., they have a higher carbon content – and are used in steel-making and other segments of the metallurgical industries. Technical characteristics of the various grades of anthracite are as follows:

Standard grade anthracite High grade anthracite High grade anthracite Coke
Moisture (maximum) 15% 15% 13% 5%
Ash (maximum) 20% 15% 12% 14%
Volatiles (maximum) 10% 10% 5% 2%
Fixed carbon (minimum) 73% 80% 85% 84%
Sulfur (maximum) 1% 1% 0.6% 0.8%
Group of breaker boys, from a 1910 photograph by Lewis Hine

Anthracite is divided by size mainly into applications that need lumps (typically larger than 10 mm) - various industrial processes where it replaces metallurgical coke, and domestic fuel - and those that need fines (less than 10 mm), such as sintering and pelletising.[16]

The common American classification by size is as follows:

Lump, steamboat, egg and stove coals, the latter in two or three sizes, all three being above  1 1⁄2 in (38 mm) size on round-hole screens.

High grade

High grade (HG) and ultra high grade (UHG) anthracite are the highest grades of anthracite coal. They are the purest forms of coal, having the highest degree of coalification, the highest carbon count and energy content and the fewest impurities (moisture, ash and volatiles).

High grade and ultra high grade anthracite are harder than standard grade anthracite, and have a higher relative density. An example of a chemical formula for high-grade anthracite would be C240H90O4NS,[19] representing 93.5% carbon.[20] UHG anthracite typically has a minimum carbon content of 95%.

They also differ in usage from standard grade anthracite (used mainly for power generation), being employed mainly in metallurgy as a cost-efficient substitute for coke in processes such as sintering and pelletising, as well as pulverised coal injection (PCI) and direct injection into blast furnaces. They can also be used in water purification and domestically as a smokeless fuel.

HG and UHG anthracite account for a small percentage of the total anthracite market. The major producing countries are Russia, Ukraine, Vietnam, South Africa and the US.

Classification Minimum Size (inches) Maximum Size (inches)
Chestnut 7/8  1 1⁄2
Pea 9/16 7/8
Buckwheat 3/8 9/16
Rice 3/16 3/8
Barley 3/32 3/16

The primary sizes used in the United States for domestic heating are Chestnut, Pea, Buckwheat and Rice, with Chestnut and Rice being the most popular. Chestnut and Pea are used in hand fired furnaces while the smaller Rice and Buckwheat are used in automatic stoker furnaces. Rice is currently the most sought after size due to the ease of use and popularity of that type of furnace.

In South Wales a less elaborate classification is adopted, but great care is exercised in hand-picking and cleaning the coal from particles of pyrites in the higher qualities known as best malting coals, which are used for kiln-drying malt.

Anthracite dust can be made into briquettes and is sold in the United Kingdom under trade names such as Phurnacite, Ancit and Taybrite.

Underground fires

See also: Coal seam fire
Culm dump of anthracite tailings on fire near Scranton, Pennsylvania

Historically from time to time, underground seams of coal have caught fire, often from careless or unfortunate mining activities. The pocket of ignited coal is fed oxygen by vent paths that have not yet been discovered. These can smolder for years. Commonly, exhaust vents in populated areas are soon sensed and are sealed while vents in uninhabited areas remain undiscovered. Occasionally, vents are discovered via fumes sensed by passers-by, often in forested areas. Attempts to extinguish those remaining have at times been futile, and several such combustion areas exist today. The existence of an underground combustion site can sometimes be identified in the winter where fallen snow is seen to be melted by the warmth conducted from below. Proposals for harnessing this heat as geothermal energy have not been successful.

A vein of anthracite that caught fire in Centralia, Pennsylvania in 1962 has been burning ever since, turning the once thriving borough into a ghost town.[21]

Major reserves

Among current producers, Russia, China and Ukraine have the largest estimated recoverable reserves of anthracite. Other countries with substantial reserves include Vietnam and North Korea.[22]

Geologically, the largest most concentrated anthracite deposit in the world is found in northeastern Pennsylvania, United States. Locally called the Coal Region, the deposit contains 480 square miles of coal bearing rock which originally held 22.8 billion short tons (20.68 billion tonnes) of anthracite.[23] (The geographic region is roughly 100 miles (161 km) in length and 30 miles (48 km) in width.) Because of historical mining and development of the lands overlying the coal, it is estimated that 7 billion short tons (6.3 billion tonnes) of minable reserves remain. The United States also contains several smaller deposits of anthracite, such as those historically mined in Crested Butte, Colorado.

The Groundhog Anthracite Deposit, located in British Columbia, Canada, is the largest previously undeveloped anthracite deposit in the world. It is owned by Australian publicly listed company, Atrum Coal and boasts 1.57 billion tonnes of high grade anthracite.[24]

Anthracites of newer Tertiary or Cretaceous age are found in the Crowsnest Pass part of the Rocky Mountains in Canada and at various places in the Andes in Peru.

See also

References

Citations

  1. ↑ "MIN 454: Underground Mining Methods handout; from course at the University of Alaska Fairbanks". Archived from the original on 26 March 2009. Retrieved 2009-05-05.
  2. ↑ R. Stefanenko (1983). Coal Mining Technology: Theory and Practice. Society for Mining Metallurgy. ISBN 0-89520-404-5.
  3. ↑ World Coal Association - The Coal Resource Archived October 15, 2009, at the Wayback Machine.
  4. 1 2 U.S. Energy Information Administration 2010 international energy statistics
  5. ↑ "anthracite", The Oxford English Dictionary. 2nd ed. 1989. OED Online. Oxford University Press. Retrieved 2010-06-26.
  6. 1 2 3 EB (1878).
  7. ↑ Not to be confused with the German Steinkohle[8] or Dutch steenkool which are broader terms meaning all varieties of coal of a stonelike hardness and appearance, like bituminous coal and often anthracite as well, as opposed to lignite, which is softer.
  8. 1 2 3 4 EB (1911).
  9. ↑ US Geological Survey and US Department of Mines (1968). Mineral Resources of the Appalachian Region; USGS Professional Paper 580. USGS. p. 126.
  10. ↑ Rosenberg 1982, pp. 89
  11. ↑ Owen, George, The Description of Pembrokeshire, Dillwyn Miles (Ed), Gomer Press, Llandysul, 1994, ISBN 1-85902-120-4, pp 60, 69–70, 90–95, 139, 255
  12. ↑ Rosenberg, Nathan (1982). Inside the Black Box: Technology and Economics. Cambridge, New York: Cambridge University Press. p. 88. ISBN 0-521-27367-6.
  13. ↑ Underwood, Rodman L. (2008). Waters of Discord: The Union Blockade of Texas During the Civil War. McFarland. p. 55. ISBN 978-0-7864-3776-4.
  14. ↑ Urbina, Ian (June 10, 2008). "King Coal Country Debates a Sacrilege, Gas Heat". The New York Times. Retrieved June 21, 2008.
  15. ↑ uksmokecontrolareas.co.uk
  16. 1 2 Petmin Annual Report 2011 Archived May 5, 2012, at the Wayback Machine.
  17. ↑ http://coaldiver.org/coal-diver/Pennsylvania-Anthracite, retrieved January 3, 2011
  18. ↑ http://www.dep.state.pa.us/dep/deputate/enved/go_with_inspector/coalmine/Anthracite_Coal_Mining.htm Archived January 16, 2005, at the Wayback Machine.
  19. ↑ "Coal characteristics: Indiana Center for Coal Technology Research Basic Facts File #8" (PDF). Indiana Center for Coal Technology Research. Retrieved 15 May 2012.
  20. ↑ Molecular mass calculator
  21. ↑ Bellows, Alan (2006) "The Smoldering Ruins of Centralia" DamnInteresting.com (accessed August 29, 2006)
  22. ↑ Marston - Anthracite production and exports: A world map
  23. ↑ http://www.libraries.psu.edu/content/dam/psul/up/emsl/documents/pags_reports/PR%20no.130.pdf[]
  24. ↑ http://atrumcoal.com/projects/project-1/

Further reading

Primary sources

External links

Wikimedia Commons has media related to Anthracite.
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