Ashburtonite

Ashburtonite
General
Category Cyclosilicates
Formula
(repeating unit)
HPb4Cu4Si4O12(HCO3)4(OH)4Cl
Strunz classification 9.CF.05
Crystal system Tetragonal
Crystal class Dipyramidal (4/m)
H-M symbol: (4/m)
Space group I4/m
Unit cell a = 14.23, c = 6.1 [Å]; Z = 2
Identification
Color Blue
Crystal habit Prismatic, needle like in clusters
Cleavage None
Tenacity Brittle
Luster Vitreous to adamantine
Streak light blue
Diaphaneity Transparent
Specific gravity Greater than 4.07, calculated 4.69
Optical properties Uniaxial (+)
Refractive index nω = 1.786 nε = 1.800
Birefringence 0.0140
References [1][2][3][4]

Ashburtonite is a rare lead copper silicate-bicarbonate mineral with formula: HPb4Cu2+4Si4O12(HCO3)4(OH)4Cl.[4]

Geological occurrence

Ashburtonite was first described as a secondary mineral in a shear zone in a series of shales and graywackes. It is an alteration product of galena and chalcopyrite.[3] The secondary minerals within the shear consist of carbonates, arsenates, and sulfates of lead and copper, and to a much lesser extent of zinc and iron.[4] Ashburtonite is associated with beudantite, brochantite, caledonite, cerussite, diaboleite, duftite, malachite, plattnerite, adamite, antlerite, bayldonite, bindheimite, carminite, chenevixite, chlorargyrite, chrysocolla, cinnabar, hemimorphite, hydrozincite, jarosite, lavendulan, linarite, mimetite, olivenite, paratacamite, and rosasite.

Ashburtonite was first described in 1991 for an occurrence in the Anticline prospects 11 km (6.8 mi) southwest of Ashburton Downs in the Capricorn Range of Western Australia.[3] It has also been reported from the Tonopah–Belmont Mine in the Big Horn Mountains of Maricopa County, Arizona.[2]

References


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