Leuckart thiophenol reaction

The Leuckart thiophenol reaction is the decomposition of a diazoxanthate, by gentle warming in a slightly acidic cuprous medium, to its corresponding aryl xanthates which give aryl thiols on alkaline hydrolysis and aryl thioethers on further warming.

This reaction was first reported by Rudolf Leuckart in 1890.[1][2] [3]

References

  1. ↑ Leuckart, Rudolf (30 December 1889). "Eine neue Methode zur Darstellung aromatischer Mercaptane". Journal für Praktische Chemie. 41 (1): 179–224. doi:10.1002/prac.18900410114.
  2. ↑ Fukushima, D. K.; Tarbell, D. S. (1947). "m-THIOCRESOL". Organic Syntheses. 27: 81. doi:10.15227/orgsyn.027.0081.
  3. ↑ Merck Index 14th Ed.


This article is issued from Wikipedia - version of the 3/28/2015. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.