Paper

For other uses, see Paper (disambiguation).

Different types of paper: carton, tissue paper
Paper

"Paper" in Traditional (top) and Simplified (bottom) Chinese characters
Traditional Chinese 紙
Simplified Chinese 纸

Paper is a thin material produced by pressing together moist fibres of cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets. It is a versatile material with many uses, including writing, printing, packaging, cleaning, and a number of industrial and construction processes.

The pulp papermaking process is said to have been developed in China during the early 2nd century AD, possibly as early as the year 105 A.D.,[1] by the Han court eunuch Cai Lun, although the earliest archaeological fragments of paper derive from the 2nd century BC in China.[2] The modern pulp and paper industry is global, with China leading its production and the United States right behind it.

History

Main article: History of paper
Hemp wrapping paper, China, circa 100 BC.

The oldest known archaeological fragments of the immediate precursor to modern paper, date to the 2nd century BC in China. The pulp papermaking process is ascribed to Cai Lun, a 2nd-century AD Han court eunuch.[2] With paper as an effective substitute for silk in many applications, China could export silk in greater quantity, contributing to a Golden Age.

Its knowledge and uses spread from China through the Middle East to medieval Europe in the 13th century, where the first water powered paper mills were built.[3] Because of paper's introduction to the West through the city of Baghdad, it was first called bagdatikos.[4] In the 19th century, industrial manufacture greatly lowered its cost, enabling mass exchange of information and contributing to significant cultural shifts. In 1844, the Canadian inventor Charles Fenerty and the German F. G. Keller independently developed processes for pulping wood fibres.[5]

Early sources of Fiber

Ancient Sanskrit on Hemp based Paper. Hemp Fiber was commonly used in the production of paper from 200 BCE to the Late 1800's.
See also: wood pulp and deinking

Before the industrialisation of the paper production the most common fibre source was recycled fibres from used textiles, called rags. The rags were from hemp, linen and cotton.[6] A process for removing printing inks from recycled paper was invented by German jurist Justus Claproth in 1774.[6] Today this method is called deinking. It was not until the introduction of wood pulp in 1843 that paper production was not dependent on recycled materials from ragpickers.[6]

Etymology

Further information: Papyrus

The word "paper" is etymologically derived from Latin papyrus, which comes from the Greek πάπυρος (papuros), the word for the Cyperus papyrus plant.[7][8] Papyrus is a thick, paper-like material produced from the pith of the Cyperus papyrus plant, which was used in ancient Egypt and other Mediterranean cultures for writing before the introduction of paper into the Middle East and Europe.[9] Although the word paper is etymologically derived from papyrus, the two are produced very differently and the development of the first is distinct from the development of the second. Papyrus is a lamination of natural plant fibres, while paper is manufactured from fibres whose properties have been changed by maceration.[2]

Papermaking

Main article: Papermaking

Chemical pulping

To make pulp from wood, a chemical pulping process separates lignin from cellulose fibres. This is accomplished by dissolving lignin in a cooking liquor, so that it may be washed from the cellulose; this preserves the length of the cellulose fibres. Paper made from chemical pulps are also known as wood-free papers–not to be confused with tree-free paper; this is because they do not contain lignin, which deteriorates over time. The pulp can also be bleached to produce white paper, but this consumes 5% of the fibres; chemical pulping processes are not used to make paper made from cotton, which is already 90% cellulose.

The microscopic structure of paper: Micrograph of paper autofluorescing under ultraviolet illumination. The individual fibres in this sample are around 10 µm in diameter.

There are three main chemical pulping processes: the sulfite process dates back to the 1840s and it was the dominant method extent before the second world war. The kraft process, invented in the 1870s and first used in the 1890s, is now the most commonly practiced strategy, one of its advantages is the chemical reaction with lignin, that produces heat, which can be used to run a generator. Most pulping operations using the kraft process are net contributors to the electricity grid or use the electricity to run an adjacent paper mill. Another advantage is that this process recovers and reuses all inorganic chemical reagents. Soda pulping is another specialty process used to pulp straws, bagasse and hardwoods with high silicate content.

Mechanical pulping

There are two major mechanical pulps, the thermomechanical one (TMP) and groundwood pulp (GW). In the TMP process, wood is chipped and then fed into steam heated refiners, where the chips are squeezed and converted to fibres between two steel discs. In the groundwood process, debarked logs are fed into grinders where they are pressed against rotating stones to be made into fibres. Mechanical pulping does not remove the lignin, so the yield is very high, >95%, however it causes the paper thus produced to turn yellow and become brittle over time. Mechanical pulps have rather short fibres, thus producing weak paper. Although large amounts of electrical energy are required to produce mechanical pulp, it costs less than the chemical kind.

De-inked pulp

Paper recycling processes can use either chemically or mechanically produced pulp; by mixing it with water and applying mechanical action the hydrogen bonds in the paper can be broken and fibres separated again. Most recycled paper contains a proportion of virgin fibre for the sake of quality; generally speaking, de-inked pulp is of the same quality or lower than the collected paper it was made from.

There are three main classifications of recycled fibre:.

Recycled papers can be made from 100% recycled materials or blended with virgin pulp, although they are (generally) not as strong nor as bright as papers made from the latter.

Additives

Besides the fibres, pulps may contain fillers such as chalk or china clay, which improve its characteristics for printing or writing. Additives for sizing purposes may be mixed with it and/or applied to the paper web later in the manufacturing process; the purpose of such sizing is to establish the correct level of surface absorbency to suit ink or paint.

Producing paper

Main articles: Paper machine and papermaking

The pulp is fed to a paper machine where it is formed as a paper web and the water is removed from it by pressing and drying.

Pressing the sheet removes the water by force; once the water is forced from the sheet, a special kind of felt, which is not to be confused with the traditional one, is used to collect the water; whereas when making paper by hand, a blotter sheet is used instead.

Drying involves using air and/or heat to remove water from the paper sheets; in the earliest days of paper making this was done by hanging the sheets like laundry; in more modern times various forms of heated drying mechanisms are used. On the paper machine the most common is the steam heated can dryer. These can reach temperatures above 200 °F (93 °C) and are used in long sequences of more than 40 cans; where the heat produced by these can easily dry the paper to less than 6% moisture.

Finishing

The paper may then undergo sizing to alter its physical properties for use in various applications.

Paper at this point is uncoated. Coated paper has a thin layer of material such as calcium carbonate or china clay applied to one or both sides in order to create a surface more suitable for high-resolution halftone screens. (Uncoated papers are rarely suitable for screens above 150 lpi.) Coated or uncoated papers may have their surfaces polished by calendering. Coated papers are divided into matte, semi-matte or silk, and gloss. Gloss papers give the highest optical density in the printed image.

The paper is then fed onto reels if it is to be used on web printing presses, or cut into sheets for other printing processes or other purposes. The fibres in the paper basically run in the machine direction. Sheets are usually cut "long-grain", i.e. with the grain parallel to the longer dimension of the sheet.

Paper grain

All paper produced by paper machines as the Fourdrinier Machine are wove paper, i.e. the wire mesh that transports the web leaves a pattern that has the same density along the paper grain and across the grain. Textured finishes, watermarks and wire patterns imitating hand-made laid paper can be created by the use of appropriate rollers in the later stages of the machine.

Wove paper does not exhibit "laidlines", which are small regular lines left behind on paper when it was handmade in a mould made from rows of metal wires or bamboo. Laidlines are very close together. They run perpendicular to the "chainlines", which are further apart. Handmade paper similarly exhibits "deckle edges", or rough and feathery borders.[11]

Applications

Paper can be produced with a wide variety of properties, depending on its intended use.

It is estimated that paper-based storage solutions captured 0.33% of the total in 1986 and only 0.007% in 2007, even though in absolute terms, the world's capacity to store information on paper increased from 8.7 to 19.4 petabytes.[12] It is estimated that in 1986 paper-based postal letters represented less than 0.05% of the world's telecommunication capacity, with sharply decreasing tendency after the massive introduction of digital technologies.[12]

Types, thickness and weight

Main articles: Paper size, Grammage, and Paper density
Card and paper stock for crafts use comes in a wide variety of textures and colors.

The thickness of paper is often measured by caliper, which is typically given in thousandths of an inch in the United States and in micrometers (µm) in the rest of the world.[13] Paper may be between 0.07 and 0.18 millimetres (0.0028 and 0.0071 in) thick.[14]

Paper is often characterized by weight. In the United States, the weight assigned to a paper is the weight of a ream, 500 sheets, of varying "basic sizes", before the paper is cut into the size it is sold to end customers. For example, a ream of 20 lb, 8.5 in × 11 in (216 mm × 279 mm) paper weighs 5 pounds, because it has been cut from a larger sheet into four pieces.[15] In the United States, printing paper is generally 20 lb, 24 lb, or 32 lb at most. Cover stock is generally 68 lb, and 110 lb or more is considered card stock.

In Europe, and other regions using the ISO 216 paper sizing system, the weight is expressed in grammes per square metre (g/m2 or usually just g) of the paper. Printing paper is generally between 60 g and 120 g. Anything heavier than 160 g is considered card. The weight of a ream therefore depends on the dimensions of the paper and its thickness.

Most commercial paper sold in North America is cut to standard paper sizes based on customary units and is defined by the length and width of a sheet of paper.

The ISO 216 system used in most other countries is based on the surface area of a sheet of paper, not on a sheet's width and length. It was first adopted in Germany in 1922 and generally spread as nations adopted the metric system. The largest standard size paper is A0 (A zero), measuring one square meter (approx. 1189 × 841 mm). Two sheets of A1, placed upright side by side fit exactly into one sheet of A0 laid on its side. Similarly, two sheets of A2 fit into one sheet of A1 and so forth. Common sizes used in the office and the home are A4 and A3 (A3 is the size of two A4 sheets).

The density of paper ranges from 250 kg/m3 (16 lb/cu ft) for tissue paper to 1,500 kg/m3 (94 lb/cu ft) for some speciality paper. Printing paper is about 800 kg/m3 (50 lb/cu ft).[16]

Paper may be classified into seven categories:[17]

Some paper types include:

Paper stability

Much of the early paper made from wood pulp contained significant amounts of alum, a variety of aluminium sulfate salts that is significantly acidic. Alum was added to paper to assist in sizing,[18] making it somewhat water resistant so that inks did not "run" or spread uncontrollably. Early papermakers did not realize that the alum they added liberally to cure almost every problem encountered in making their product would eventually be detrimental.[19] The cellulose fibres that make up paper are hydrolyzed by acid, and the presence of alum would eventually degrade the fibres until the paper disintegrated in a process that has come to be known as "slow fire". Documents written on rag paper were significantly more stable. The use of non-acidic additives to make paper is becoming more prevalent, and the stability of these papers is less of an issue.

Paper made from mechanical pulp contains significant amounts of lignin, a major component in wood. In the presence of light and oxygen, lignin reacts to give yellow materials,[20] which is why newsprint and other mechanical paper yellows with age. Paper made from bleached kraft or sulfite pulps does not contain significant amounts of lignin and is therefore better suited for books, documents and other applications where whiteness of the paper is essential.

Paper made from wood pulp is not necessarily less durable than a rag paper. The ageing behavior of a paper is determined by its manufacture, not the original source of the fibres.[21] Furthermore, tests sponsored by the Library of Congress prove that all paper is at risk of acid decay, because cellulose itself produces formic, acetic, lactic and oxalic acids.[22]

Mechanical pulping yields almost a tonne of pulp per tonne of dry wood used, which is why mechanical pulps are sometimes referred to as "high yield" pulps. With almost twice the yield as chemical pulping, mechanical pulps is often cheaper. Mass-market paperback books and newspapers tend to use mechanical papers. Book publishers tend to use acid-free paper, made from fully bleached chemical pulps for hardback and trade paperback books.

Environmental impact of paper

The production and use of paper has a number of adverse effects on the environment.

Worldwide consumption of paper has risen by 400% in the past 40 years leading to increase in deforestation, with 35% of harvested trees being used for paper manufacture. Most paper companies also plant trees to help regrow forests. Logging of old growth forests accounts for less than 10% of wood pulp,[23] but is one of the most controversial issues.

Paper waste accounts for up to 40% of total waste produced in the United States each year, which adds up to 71.6 million tons of paper waste per year in the United States alone.[24] The average office worker in the US prints 31 pages every day.[25] Americans also use on the order of 16 billion paper cups per year.

Conventional bleaching of wood pulp using elemental chlorine produces and releases into the environment large amounts of chlorinated organic compounds, including chlorinated dioxins.[26] Dioxins are recognized as a persistent environmental pollutant, regulated internationally by the Stockholm Convention on Persistent Organic Pollutants. Dioxins are highly toxic, and health effects on humans include reproductive, developmental, immune and hormonal problems. They are known to be carcinogenic. Over 90% of human exposure is through food, primarily meat, dairy, fish and shellfish, as dioxins accumulate in the food chain in the fatty tissue of animals.[27]

Future of paper

Some manufacturers have started using a new, significantly more environmentally friendly alternative to expanded plastic packaging. Made out of paper, and known commercially as paperfoam, the new packaging has mechanical properties very similar to those of some expanded plastic packaging, but is biodegradable and can also be recycled with ordinary paper.[28]

With increasing environmental concerns about synthetic coatings (such as PFOA) and the higher prices of hydrocarbon based petrochemicals, there is a focus on zein (corn protein) as a coating for paper in high grease applications such as popcorn bags.[29]

Also, synthetics such as Tyvek and Teslin have been introduced as printing media as a more durable material than paper.

See also

Notes

  1. ↑ Hogben, Lancelot. "Printing, Paper and Playing Cards". Bennett, Paul A. (ed.) Books and Printing: A Treasury for Typophiles. New York: The World Publishing Company, 1951. pp. 15–31. p. 17. & Mann, George. Print: A Manual for Librarians and Students Describing in Detail the History, Methods, and Applications of Printing and Paper Making. London: Grafton & Co., 1952. p. 77
  2. 1 2 3 Tsien 1985, p. 38
  3. ↑ Burns 1996, pp. 417f.
  4. ↑ Murray, Stuart A. P. The Library: An illustrated History. Skyhorse Publishing, 2009, p. 57.
  5. ↑ Burger, Peter. Charles Fenerty and his Paper Invention. Toronto: Peter Burger, 2007. ISBN 978-0-9783318-1-8 pp. 25–30
  6. 1 2 3 Göttsching, Lothar; Pakarinen, Heikki (2000), "1", Recycled Fiber and Deinking, Papermaking Science and Technology, 7, Finland: Fapet Oy, pp. 12–14, ISBN 952-5216-07-1
  7. ↑ πάπυρος, Henry George Liddell, Robert Scott, A Greek-English Lexicon, on Perseus
  8. ↑ papyrus, on Oxford Dictionaries
  9. ↑ "Papyrus definition". Dictionary.com. Retrieved 20 November 2008.
  10. ↑ Natural Resource Defense Council
  11. ↑ "Document Doubles" in a virtual museum exhibition at Library and Archives Canada
  12. 1 2 "The World’s Technological Capacity to Store, Communicate, and Compute Information", especially Supporting online material, Martin Hilbert and Priscila López (2011), Science (journal), 332(6025), 60-65; free access to the article through here: martinhilbert.net/WorldInfoCapacity.html
  13. ↑ "Paper Thickness Chart", Case Paper Company Inc.
  14. ↑ "Thickness of a Piece of Paper", hyperTextbook.com
  15. ↑ McKenzie, Bruce G., The Hammermill Guide to Desktop Publishing in Business, p. 144, Hammermill Papers, 1989.
  16. ↑ "Density of paper and paperboard". PaperOnWeb. Retrieved 31 October 2007.
  17. ↑ Johnson, Arthur (1978). The Thames and Hudson Manual of Bookbinding. London: Thames and Hudson.
  18. ↑ Biermann, Christopher J. (1993). Handbook of Pulping and Papermaking. San Diego: Academic Press. ISBN 0-12-097360-X.
  19. ↑ Clark, James d'A. (1985). Pulp Technology and Treatment for Paper (2nd ed.). San Francisco: Miller Freeman Publications. ISBN 0-87930-164-3.
  20. ↑ Fabbri, Claudia; Bietti, Massimo; Lanzalunga, Osvaldo. "Generation and Reactivity of Ketyl Radicals with Lignin Related Structures. On the Importance of the Ketyl Pathway in the Photoyellowing of Lignin Containing Pulps and Papers". J. Org. Chem. 2005 (70): 2720–2728. doi:10.1021/jo047826u.
  21. ↑ Erhardt, D.; Tumosa, C. (2005). "Chemical Degradation of Cellulose in Paper over 500 years". Restaurator: International Journal for the Preservation of Library and Archival Material. 26: 155. doi:10.1515/rest.2005.26.3.151.
  22. ↑ "The Deterioration and Preservation of Paper: Some Essential Facts". Library of Congress. Retrieved 7 January 2015. Research by the Library of Congress has demonstrated that cellulose itself generates acids as it ages, including formic, acetic, lactic, and oxalic acids
  23. ↑ Martin, Sam (2004). "Paper Chase". Ecology Communications, Inc. Archived from the original on 19 June 2007. Retrieved 21 September 2007.
  24. ↑ EPA (28 June 2006). "General Overview of What's In America's Trash". United States Environmental Protection Agency. Retrieved 4 April 2012.
  25. ↑ Groll, T. 2015 In vielen Büros wird unnötig viel ausgedruckt, Zeit Online, 20 June 2015.
  26. ↑ "Effluents from Pulp Mills using Bleaching - PSL1". ISBN 0-662-18734-2 DSS. Health Canada. 1991. Retrieved 21 September 2007.
  27. ↑ "Dioxins and their effects on human health". World Health Organization. June 2014. Retrieved 7 January 2015. More than 90% of human exposure is through food
  28. ↑ PaperFoam Carbon Friendly Packaging
  29. ↑ Barrier compositions and articles produced with the compositions cross-reference to related application

References

Further reading

Look up paper in Wiktionary, the free dictionary.
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