Boron triiodide

Boron triiodide[1]
Names
IUPAC name
triiodoborane
Identifiers
13517-10-7 N
3D model (Jmol) Interactive image
ChemSpider 75378 YesY
ECHA InfoCard 100.033.492
PubChem 83546
RTECS number ED7400000
Properties
BI3
Molar mass 391.52 g/mol
Appearance crystalline solid
Density 3.35 g/cm3 (50 °C)
Melting point 49.9 °C (121.8 °F; 323.0 K)
Boiling point 210 °C (410 °F; 483 K)
reacts
Solubility soluble in CCl4, CS2, benzene, chloroform
0D
Structure
trigonal
Thermochemistry
71 J/mol K
200 J/mol K
-37.2 kJ/mol
Hazards
Safety data sheet Sigma-Aldrich
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazards (white): no codeNFPA 704 four-colored diamond
0
3
0
Flash point −18 °C (0 °F; 255 K)
Related compounds
Related compounds
 Boron trifluoride
Boron trichloride
Boron tribromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Boron triiodide is a chemical compound of boron and iodine with chemical formula BI3. It has a trigonal planar molecular geometry. It is a crystalline solid, which reacts vigorously with water to form boric acid.[2] Its dielectric constant is 5.38 and its heat of vaporization is 40.5 kJ/mol. At extremely high pressures, BI3 becomes metallic at ~23 GPa and is a superconductor above ~27 GPa. [3]

Preparation

Boron triiodide can be prepared by the reaction of boron with iodine at 209.5 °C or 409.1 °F. It can also be prepared by this other method: (this reaction requires high temperature).

References

  1. ↑ Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  2. ↑ http://www.sciencemadness.org/talk/files.php?pid=110072&aid=4171
  3. ↑ http://journals.aps.org/prb/abstract/10.1103/PhysRevB.82.094506
HI He
LiI BeI2 BI3 CI4 NI3 I2O4,
I2O5,
I4O9		 IF,
IF3,
IF5,
IF7		 Ne
NaI MgI2 AlI3 SiI4 PI3,
P2I4		 S ICl,
ICl3		 Ar
KI CaI2 Sc TiI4 VI3 CrI3 MnI2 FeI2 CoI2 NiI2 CuI ZnI2 Ga2I6 GeI2,
GeI4 		AsI3 Se IBr Kr
RbI SrI2 Y ZrI4 Nb Mo Tc Ru Rh Pd AgI CdI2 InI3 SnI4,
SnI2		 SbI3 TeI4 I Xe
CsI BaI2   Hf Ta W Re Os Ir Pt AuI Hg2I2,
HgI2		 TlI PbI2 BiI3 Po AtI Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce Pr Nd Pm SmI2 Eu Gd TbI3 Dy Ho Er Tm Yb Lu
Ac ThI4 Pa UI3,
UI4		 Np Pu Am Cm Bk Cf Es Fm Md No Lr
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