Pongamia oil

Pongamia oil is derived from the seeds of the Millettia pinnata tree, which is native to tropical and temperate Asia. Millettia pinnata, also known as Pongamia pinnata or Pongamia glabra, is common throughout Asia and thus has many different names in different languages, many of which have come to be used in English to describe the seed oil derived from M. pinnata; Pongamia is often used as the generic name for the tree and is derived from the genus the tree was originally placed in.[1]

Other English names for this oil include Honge oil (from Kannada), Kanuga oil (from Telugu), Karanja oil (from Hindi), and Pungai oil (from Tamil).

Cultivation

Pods and seeds of Millettia pinnata

Millettia pinnata is native to South and Southeast Asia. Known in various languages as Indian beech, Pongam, Karanja, Honge, Kanuga, and Naktamala, it is now grown all over the world. Typically the plant starts yielding pods from the fifth year on with the yields increasing each year until it stabilizes around the tenth year. Seeds are usually harvested in the spring, each seed weighing from about 1.1 grams (0.039 oz) to 1.8 grams (0.063 oz). The yield per tree can range from about 10 kilograms (22 lb) to more than 50 kilograms (110 lb) depending on conditions, with an average of 1500-1700 seeds per kilogram. Historically the pods are removed from the trees by beating the branches with sticks and decorticated using mallets or stones. Research is ongoing into mechanical harvesting methods.

The basic nutritional components of Millettia pinnata seeds may change depending on the season and maturity of the tree but in general are as follows:[2]

Component Percentage
Oil 27% - 39%
Protein 17% - 37%
Starch 6% - 7%
Crude fiber 5% - 7%
Moisture 15% - 20%
Ash 2% - 3%

Description

Pongamia oil is extracted from the seeds by expeller pressing, cold pressing, or solvent extraction. The oil is yellowish-orange to brown in color. It is toxic and will induce nausea and vomiting if eaten, but it is used in many traditional remedies. It has a high content of triglycerides, and its disagreeable taste and odor are due to bitter flavonoid constituents including karanjin, pongamol, tannin and karanjachromene.[2]

Millettia pinnata has a number of different varieties but little research has been published on the differences between them.[3] This combined with variances in soil and weather can change the specific composition of Pongamia oil. Typically Pongamia oil is composed of the following fatty acids:[2][4]

Fatty acid Nomenclature Percentage
Palmitic C16:0 3.7% – 7.9%
Stearic C18:0 2.4% – 8.9%
Oleic C18:1 44.5% – 71.3%
Linoleic C18:2 10.8% – 18.3%
Linolenic C18:3 2.6%
Arachidic C20:0 2.2% – 4.7%
Eicosenoic C20:1 9.5% – 12.4%
Behenic C22:0 4.2% – 5.3%
Lignoceric C24:0 1.1% – 3.5%

The physical properties of crude Pongamia oil are as follows:[4][5]

Property Unit Value
Acid value mg KOH/g 4.0 - 12
Calorific value kcal/kg 8742
Cetane number 42
Density g/cm3 0.924
Iodine value g/100 g 86.5 - 87
Saponification value mg KOH/g 184 - 187
Specific gravity 0.925
Unsaponifiable matter % w/w 2.6 - 2.9
Viscosity mm2/sec 40.2
Boiling point °C 316
Cloud point °C 3.5
Fire Point °C 230
Flash point °C 225
Pour point °C -3.0

Uses

Traditional

It has been used as lamp oil, in leather tanning, in soap making, and as a lubricant for thousands of years. Its toxicity, as well as its color, bitter taste, and disagreeable odour, keep it from being used in cooking, but it does have uses in traditional medicine for treating skin disease and liver disease.[1]

There is also research indicating that the oil can be used as a natural insecticide.[6]

It also used as a fish poison, as the metabolites karanjin and pongamol are both toxic to fish.[7][8]

Biodiesel

Many studies have been done to convert Pongamia oil into biodiesel.[9][10][11][12] The following table shows the physical properties of the methyl esters of Pongamia oil versus the ASTM D6751 and EN 14214 biodiesel standards:[4][5]

Property Unit Methyl esters ASTM D6751 EN 14214
Acid value mg KOH/g 0.46 - 0.5 <0.8 <0.5
Calorific value kcal/kg 3700
Cetane Number 41.7 - 56 >45 >51
Density at 15°C g/cm3 0.86 - 0.88 0.87 - 0.89 0.86 - 0.90
Viscosity at 40°C mm2/s 4.77 1.9 - 6.0 3.5 - 5.0
Iodine value g/100 g 86.5 - 91 <120
Oxidation Stability at 110°C h 2.24 >6
Saponification value mg KOH/g 184 - 187
Unsaponifiable matter % w/w 2.6 - 2.9
Boiling point °C 316
Cloud point °C 19 0/-15 †
Fire Point °C 230
Flash point °C 174 >130 >101
Pour point °C 15
† This is not a property of the EN 14214 standard; it is country specific standard for summer/winter seasons.

The comparison of the methyl esters of Pongamia oil to the ASTM D6751 standard for biodiesel fuels shows that processed Pongamia oil is within the standards. Against the European EN 14214 standards, Pongamia oil does not meet the storage stability standard; Oxidation stability needs to be a minimum of 6 hours at 110°C, but the stability of processed Pongamia oil is only 2.24 hours.[4] Research has shown that jatropha or pongamia oil can be mixed with palm oil to achieve an improved low-temperature viscosity than pure palm oil and a higher oxidation stability than pure jatropha or pongamia oil.[13] In addition, the methyl esters of Pongamia oil have a cloud point of 19°C, which is outside some country specific standards, and a pour point of 15°C both of which would be problematic in lower temperature climates.[4]

See also

References

  1. 1 2 "Pongamia Factsheet" (PDF). Retrieved 2013-10-02.
  2. 1 2 3 Factsheet from New crops at Purdue University
  3. ↑ "Weed Risk Assessment : Pongamia" (PDF). Daff.qld.gov.au. Retrieved 2013-11-21.
  4. 1 2 3 4 5 Ashok Pandey (2008). Handbook of Plant-Based Biofuels. CRC. pp. 255–266. ISBN 1-56022-175-5.
  5. 1 2 "Detail study on the Properties of Pongamia Pinnata (Karanja) for the Production of Biofuel" (PDF). Isca.in. Retrieved 2013-11-21.
  6. ↑ Scott, Paul T.; Pregelj, Lisette; Chen, Ning; Hadler, Johanna S.; Djordjevic, Michael A.; Gresshoff, Peter M. (2008). "Pongamia pinnata: An Untapped Resource for the Biofuels Industry of the Future". BioEnergy Research. 1: 2. doi:10.1007/s12155-008-9003-0.
  7. ↑ Arole, SR (2010). "Pongamia pinnata L: A Comprehensive Review" (PDF). International Journal of PharmTech Research.
  8. ↑ S., Mahli, S.; P., Basu, S.; P., Sinha, K.; C., Banerjee, N. "Pharmacological effects of karanjin and pongamol [from seed oil of Pongamia pinnata].". www.cabdirect.org. Retrieved 2016-03-03.
  9. ↑ Meher, L C; Naik, S N; Das, L M (November 2004). "Methanolysis of Pongamia pinnata (karanja) oil for production of biodiesel" (PDF). Journal of Scientific & Industrial Research. 63: 913–918.
  10. ↑ Karmee, Sanjib Kumar; Chadha, Anju (September 2005). "Preparation of biodiesel from crude oil of Pongamia pinnata". Bioresour. Technol. 96 (13): 1425–9. doi:10.1016/j.biortech.2004.12.011. PMID 15939268.
  11. ↑ Moser, Bryan R. (2009). "Biodiesel production, properties, and feedstocks" (PDF). In Vitro Cell.Dev.Biol. — Plant. 46: 229–266. doi:10.1007/s11627-009-9204-z.
  12. ↑ Mathiyazhagan, M.; Ganapathi, A.; Jaganath, B.; Renganayaki, N.; Sasireka, N. (April 2011). "Production of Biodiesel from Non-edible plant oils having high FFA content". International Journal of Chemical and Environmental Engineering. 2 (2): 119–122.
  13. ↑ Amit Sarin (2012). Biodiesel: Production and Properties. Royal Society of Chemistry. p. 233. ISBN 9781849734707.
This article is issued from Wikipedia - version of the 3/3/2016. The text is available under the Creative Commons Attribution/Share Alike but additional terms may apply for the media files.